2D natural convection flows in tilted cavities: Porous media and homogeneous fluids

Natural convection flows are studied numerically for porous media and homogeneous fluids inside a rectangular cavity with inclination. These thermal fluid flows are considered under the respective two-dimensional unsteady Boussinesq approximation in stream function and vorticity variables. The study depends on the Rayleigh number, angle of inclination, and the aspect ratio of the cavity. At the validation stage our results are in good agreement with those reported by other authors. Results suppose to be new are presented either for angles of inclination not reported before or for high Rayleigh numbers with large aspect ratios. In rectangular porous cavities with Rayleigh number 10² multiple cells appear for some angles. In homogeneous fluids, for Rayleigh numbers of the order of 10⁵–10⁶ in large enough vertical cavities at most secondary cells appear for some angles and the flow becomes more complex and looks like to be oscillatory.     

Association of indigo with zeolites for improved color stabilization

The durability of an organic color and its resistance against external chemical agents and exposure to light can be significantly enhanced by hybridizing the natural dye with a mineral. In search for stable natural pigments, the present work focuses on the association of indigo blue with several zeolitic matrices (LTA zeolite, mordenite, MFI zeolite). The manufacturing of the hybrid pigment is tested under varying oxidizing conditions, using Raman and ultraviolet-visible (UV-Vis) spectrometric techniques. Blending indigo with MFI is shown to yield the most stable composite in all of our artificial indigo pigments. In the absence of defects and substituted cations such as aluminum in the framework of the MFI zeolite matrix, we show that matching the pore size with the dimensions of the guest indigo molecule is the key factor. The evidence for the high color stability of indigo@MFI opens a new path for modeling the stability of indigo in various alumino-silicate substrates such as in the historical Maya Blue pigment.     

Cactus stem (Opuntia ficus‐indica Mill): anatomy,physiology and chemical composition with emphasis on its biofunctional properties

Cactus stem (Opuntia ficus‐indica Mill) is native to Mesoamerica and marketed in different forms such as fresh, frozen or pre‐cooked. Worldwide, this vegetable is recognized for its pharmaceutical actions, including its antioxidant, diuretic, anticarcinogenic, anti‐inflammatory, anti‐diabetic, and anti‐hypercholesterolemic properties, as well as their antiviral and antispermatogenic effects. However, not all of these properties have been associated with its chemical composition; therefore, this review aims to present and integrate information available on the physiology and anatomy of cactus stem and its chemical composition, focusing on some of the many factors that determine its biofunctionality. © 2017 Society of Chemical Industry     

The significance spectrum and EIA significance determinations

The concept of significance is fundamental to environmental impact assessment (EIA). Even though there are many guidelines describing technical characteristics of impacts (such as magnitude, geographic extent, extent and frequency) that should be considered, there has remained a long-standing need for increased clarity on how significance determinations are ultimately reached by significance determiners, those who, on behalf of governments, make a legal determination of significance in EIAs. This involves the application of societal values, in the form of subjective informed judgement, about the acceptability of the predicted impacts. This paper introduces the significance spectrum, a graphic model that illustrates a process for determining significance, using the following steps: (1) determining the threshold of significance for each valued component; (2) weighing the evidence and considering predicted impacts; (3) deciding which side of the threshold the predicted adverse impact falls on; and (4) for unacceptable impacts, deciding if mitigations can make the residual impact acceptable. Concepts such as ecological significance should not be confused with significance in EIAs, which may not only include ecological significance but also considers societal values. We provide specific steps for determining significance that help clarify this fundamental aspect that lies at the core of EIA decision-making.     

Effects of magnetic field on calcium carbonate precipitation: Ionic and particle mechanisms

There are two most widely reported mechanisms to study the effect of magnetic fields on calcium carbonate (CaCO₃) precipitate, namely ionic and particle mechanisms. The effects are most debatable because they are contrary to each other. This study explored the effects of both mechanisms in CaCO₃ deposit and total CaCO₃ precipitation using ionic and particle methods. The ionic method showed reductions in CaCO₃ deposit and total precipitation rate of CaCO₃, whereas the particle method showed the opposite results. The particle number decreased and the average particle diameter of CaCO₃ deposit increased in the ionic method. Meanwhile in the particle method, the particle number increased, average particle diameter decreased and particle aggregation of CaCO₃ was observed. XRD measurement on all deposits showed that the crystal deposit was mostly of calcite and the traces of vaterite. However, the amount of the crystal in the particle method was observed to be less than that in the ionic method, indicating that CaCO₃ deposit was more amorphous. Particle mechanism decreased the Ca²⁺ ion concentration in solution during magnetization, and ionic mechanism reduced scale (CaCO₃) formation after magnetization and separation processes. This method could be applied for decreasing water hardness and prevent the formation of scaling.     

Effect of surface resistance on cyclohexane uptake curves in Silicalite-1 crystals

Adsorption kinetics of cyclohexane in a variety of Silicalite-1 samples were measured by gravimetric uptake experiments. The kinetic appears as dependent upon the history of the crystals. Samples stored for several months before calcination (with their micropores full of template) exhibit a kinetic drop by almost an order of magnitude. Surprisingly, physico-chemicals analysis do not show any differences between these samples (no modification of their crystallinity or morphology, and no residual carbon is detected in the pore network). The kinetic drop is therefore attributed to a modification of the crystals surface, induced by a long-time contact with the template or cyclohexane molecules.Aged and as-synthesized (non-calcined) samples were etched by an HF solution, so as to “purify” the surface of the crystals. After a few minutes of treatment, the aged samples recover their initial adsorption kinetic, confirming that the kinetic drop is induced by the partial blocking of the entrance of the pores. Moreover, some of the as-synthesized crystals also show a rise of their adsorption kinetic, showing that surface resistance can be present ab initio, depending on the synthesis conditions.In an attempt to produce an accelerated aging effect, hydrothermal treatments were performed on non-calcined crystals. However, the treatments conditions are too severe, and induce variations in the crystal structure.